Synthesis and Diels-Alder reactions of 2-alkyl-5-methylene-1,3-dioxolan-4-ones and 2-alkyl-3-acyl-5-methylene-1,3-oxazolidin-4-ones: Highly exo and diastereoface selective chiral ketene equivalents

DOI: 10.1016/S0040-4039(00)70683-6

Source and publish data:

Tetrahedron Letters p. 7305 - 7308 (1989)

Update date:2022-08-02

Topics:

Authors:

Roush Roush

Essenfeld

Warmus Warmus

Brown Brown

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Article abstract of DOI:10.1016/S0040-4039(00)70683-6

Chiral dienophiles 1-3 undergo highly exo and diastereoface selective Diels-Alder reactions. The Diels-Alder reactions of 3 are also highly exo selective under Lewis acid catalyzed conditions.

Full text of DOI:10.1016/S0040-4039(00)70683-6

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