STEREOSPECIFIC C-C-BOND FORMATION WITH RABBIT MUSCLE ALDOLASE - A CHEMOENZYMATIC SYNTHESIS OF (+)-EXO-BREVICOMIN

DOI: 10.1016/S0040-4039(00)94649-5

Source and publish data:

Tetrahedron Letters p. 867 - 868 (1990)

Update date:2022-08-04

Topics:

Authors:

Schultz, M.

Waldmann, H.

Vogt, W.

Kunz, H.

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Article abstract of DOI:10.1016/S0040-4039(00)94649-5

(+)-(1S,5R,7S)-Exo-brevicomin 9, a sex pheromone of the western pine bark beetle, is synthesized using an aldol reaction catalyzed by fructose-1,6-diphosphate aldolase (EC 4.1.2.13) from rabbit muscle as the key step by which the absolute configuration of the target is established.

Full text of DOI:10.1016/S0040-4039(00)94649-5

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