oxotitanium. An Efficient Chiral Catalyst for the Asymmetric Aldol Reaction of Silyl Enol Ethers with Aldehydes

DOI: 10.1246/cl.1990.1015

Source and publish data:

Chemistry Letters p. 1015 - 1018 (1990)

Update date:2022-08-05

Topics:

Authors:

Mukaiyama, Teruaki

Inubushi, Atsuro

Suda, Shinji

Hara, Ryuichiro

Kobayashi, Shu

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Article abstract of DOI:10.1246/cl.1990.1015

In the presence of a catalytic amount of <(R)-1,1'-bi-2-naphthalene-diolato(2-)-O,O'>oxotitanium, silyl enol ethers of thioesters react with aldehydes to afford the corresponding aldol adducts in high yields with good to high ees.

Full text of DOI:10.1246/cl.1990.1015

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