oxotitanium. An Efficient Chiral Catalyst for the Asymmetric Aldol Reaction of Silyl Enol Ethers with Aldehydes

DOI: 10.1246/cl.1990.1015

Source and publish data:

Chemistry Letters p. 1015 - 1018 (1990)

Update date:2022-08-05

Topics:

Authors:

Mukaiyama, Teruaki

Inubushi, Atsuro

Suda, Shinji

Hara, Ryuichiro

Kobayashi, Shu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1015

In the presence of a catalytic amount of <(R)-1,1'-bi-2-naphthalene-diolato(2-)-O,O'>oxotitanium, silyl enol ethers of thioesters react with aldehydes to afford the corresponding aldol adducts in high yields with good to high ees.

Full text of DOI:10.1246/cl.1990.1015

Products guided by the article

Product name:S-t-butyl 3-t-butyldimethylsiloxy-5-phenyl-5-pentenethioate

Cas No:129634-39-5

R&D Labs maybe for 129634-39-5

KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district

Relevant to this article

Alkylating esters VIII. The action of the isomers of dimethylmyleran on spermatogenesis

Doi:10.1007/BF01927719
(1974)
Enantioselective Total Syntheses of Indolizidine Alkaloids 167B and 209D

Doi:10.1021/jo00302a038
(1990)
Reactions between Bis(O-alkyl dithiocarbonato)nickel(II) Complexes and Phosphines. Formation of a Dithiocarbonate Complex of Nickel(II):

Doi:10.1039/DT9870000281
(1987)
Novel second generation analogs of eribulin. Part I: Compounds containing a lipophilic C32 side chain overcome P-glycoprotein susceptibility

Doi:10.1016/j.bmcl.2011.01.111
(2011)
ASYMMETRIC SYNTHESIS WITH CHIRAL β-LACTAMS. HIGHLY STEREOSELECTIVE ALKYLATION AND ALDOL REACTION OF A CHIRAL 3-AMINO-4-STYRYL-β-LACTAM

Doi:10.1016/S0040-4039(00)94407-1
(1990)
Synthesis of [1,3, NH₂-¹⁵N₃] (5′S)-8,5′-cyclo-2′-deoxyguanosine

Doi:10.1002/jlcr.3051
(2013)

Article Doi