Organometallics p. 10 - 11 (1991)
Update date:2022-08-02
Topics:
Niecke, Edgar
Kramer, Berthold
Nieger, Martin
The 1-aza-2,3-diphosphaallyl system [Mes *PPNMes*]Li (2; Mes* = 2,4,6-t-Bu3C6H2) was obtained from the corresponding aminodiphosphene 1 by abstraction of the amine proton by n-BuLi. Reaction of 2 with nickelocene affords the metalloiminophosphane complex 3, the structure of which was determined by X-ray crystallography.
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