Journal of the Chemical Society. Chemical communications p. 1319 - 1320 (1990)
Update date:2022-08-04
Topics:
Plater, M. John
Rees, Charles W.
Treatment of 6-bromotrithiadiazepine (1) with Huenig's base in the presence of diaryldiazomethanes (2) gives the trithiadiazepyne cycloadducts (3) which undergo a deep-seated thermal rearrangement to give fused 1,2,3-dithiazoles (4), for which a mechanism
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