Tetrahedron p. 2449 - 2458 (1998)
Update date:2022-07-29
Topics: Enantioselective Alkylation Lithium Enolates Cyclic Ketones Lithium Bromide
Murakata, Masatoshi
Yasukata, Tatsuro
Aoki, Takumi
Nakajima, Makoto
Koga, Kenji
An efficient enantioselective alkylation of the lithium enolates of cyclohexanone and 1-tetralone with reactive alkyl halides was realized using a stoichiometric amount of a tetradentate chiral amine as a ligand for the lithium in the presence of lithium bromide in toluene.
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