Monatshefte fur Chemie p. 1005 - 1015 (1990)
Update date:2022-08-05
Topics:
Augustin, Manfred
Guenther, Eckhard
Meldrum's acid (1) reacts with isothiocyanates and LiH as base, yielding after alkylation the ketene-S,N-acetales 3, 4 and 5.Protonation of the lithium-thiolate 2 gives the thioamides 7 with tautomers 8, which can be methylated with diazomethane to 9.From
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