Chemical and Pharmaceutical Bulletin p. 1392 - 1396 (1991)
Update date:2022-08-03
Topics:
Kayakiri
Kasahara
Nakamura
Oku
Hashimoto
Kifunensine (1), a novel immunomodulator isolated from an actinomycete, was enantiospecifically synthesized from D-mannosamine via a double cyclization of the oxamide-aldehyde precursor with ammonia as a key step. The absolute stereochemistry of natural kifunensine was confirmed to be the D form.
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