Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

DOI: 10.1016/S0040-4039(00)97084-9

Source and publish data:

Tetrahedron Letters p. 6433 - 6436 (1990)

Update date:2022-08-06

Topics:

Authors:

Culshaw Culshaw

Walton Walton

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97084-9

Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane-1,1-dioxide respectively.

Full text of DOI:10.1016/S0040-4039(00)97084-9

Products guided by the article

Product name:5-chloro-7-thiabicyclo<4.3.0>nonane 7,7-dioxide

Cas No:137346-59-9

R&D Labs maybe for 137346-59-9

Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China

Relevant to this article

N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed a-arylation of symmetric dialkyl ketones with aryl chlorides

Doi:10.1016/j.ica.2014.07.061
(2014)
Rapid Synthesis of Boc-2′,6′-dimethyl- l -tyrosine and Derivatives and Incorporation into Opioid Peptidomimetics

Doi:10.1021/acsmedchemlett.5b00344
(2015)
The synthesis and development of 2,5-disubstituted tetrahydrofurans as potential scaffolds for diversity-oriented synthesis

Doi:10.1016/j.tetlet.2012.02.100
(2012)
A highly reactive titanium precatalyst for intramolecular hydroamination reactions.

Doi:10.1021/ol0256724
(2002)
1,2,3-Triazole: Unique ligand in promoting iron-catalyzed propargyl alcohol dehydration

Doi:10.1021/ol300778e
(2012)
Prostanoids and related compounds. VI. Synthesis of isoindolinone derivatives possessing inhibitory activity for thromboxane A₂ analog (U- 46619)-induced vasoconstriction

Doi:10.1248/cpb.41.2003
(1993)

Article Doi