Regioselectivity in the formation of cyclic sulphones from 4- and 5-alkenesulphonyl chlorides

DOI: 10.1016/S0040-4039(00)97084-9

Source and publish data:

Tetrahedron Letters p. 6433 - 6436 (1990)

Update date:2022-08-06

Topics:

Authors:

Culshaw Culshaw

Walton Walton

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97084-9

Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane-1,1-dioxide respectively.

Full text of DOI:10.1016/S0040-4039(00)97084-9

Products guided by the article

Product name:5-chloro-7-thiabicyclo<4.3.0>nonane 7,7-dioxide

Cas No:137346-59-9

R&D Labs maybe for 137346-59-9

Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Guangzhou Shiny Co., Ltd.

website:https://www.sinoshiny.com/products

Contact:+86-20-62802632;62802633

Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China

Relevant to this article

N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed a-arylation of symmetric dialkyl ketones with aryl chlorides

Doi:10.1016/j.ica.2014.07.061
(2014)
Rapid Synthesis of Boc-2′,6′-dimethyl- l -tyrosine and Derivatives and Incorporation into Opioid Peptidomimetics

Doi:10.1021/acsmedchemlett.5b00344
(2015)
The synthesis and development of 2,5-disubstituted tetrahydrofurans as potential scaffolds for diversity-oriented synthesis

Doi:10.1016/j.tetlet.2012.02.100
(2012)
A highly reactive titanium precatalyst for intramolecular hydroamination reactions.

Doi:10.1021/ol0256724
(2002)
1,2,3-Triazole: Unique ligand in promoting iron-catalyzed propargyl alcohol dehydration

Doi:10.1021/ol300778e
(2012)
Prostanoids and related compounds. VI. Synthesis of isoindolinone derivatives possessing inhibitory activity for thromboxane A₂ analog (U- 46619)-induced vasoconstriction

Doi:10.1248/cpb.41.2003
(1993)

Article Doi