Journal of the Chemical Society. Chemical communications p. 164 - 166 (1992)
Update date:2022-08-03
Topics:
Horne, Stephen
Rodrigo, Russell
A fast, general, low-temperature rearrangement of ortho-iodobenzyl esters, triggered by lithium-iodine exchange, leads to isobenzofurans which are intercepted in situ by inter and intramolecular Diels-Alder (IMDA) reactions to produce a variety of carbocycles including natural lignans and steroids.
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