Highly Stereoselective 3 + 2 Annulations by Cyclopropanation of Vinyl Ethers with Rhodium(II)-Stabilized Vinylcarbenoids Followed by a Formally Forbidden 1,3-Sigmatropic Rearrangement

DOI: 10.1021/jo00037a041

Source and publish data:

Journal of Organic Chemistry p. 3186 - 3190 (1992)

Update date:2022-07-30

Topics:

Authors:

Davies, Huw M. L.

Hu, Baihua

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Article abstract of DOI:10.1021/jo00037a041

A highly stereoselective 3 + 2 annulation has been developed by cyclopropanation of vinyl ethers with rhodium(II)-stabilized vinylcarbenoids to generate vinylcyclopropanes followed by a Et2AlCl-catalyzed 1,3-sigmatropic rearrangement.The success of this m

Full text of DOI:10.1021/jo00037a041

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