SYSTEMES DE STRECKER ET APPARENTES-XII. CATALYSE PAR LES ALDEHYDES DE L'HYDRATATION INTRAMOLECULAIRE DES α-AMINONITRILES

DOI: 10.1016/0040-4020(80)88025-2

Source and publish data:

Tetrahedron p. 2999 - 3008 (1980)

Update date:2022-08-05

Topics:

Authors:

Pascal, R.

Taillades, J.

Commeyras, A.

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Article abstract of DOI:10.1016/0040-4020(80)88025-2

Aqueous basic hydration of α-aminopropionitrile is first order either in acetaldehyde (formed by decomposition of α-aminopropionitrile) or different aldehydes added in the medium.The rate determining step involves a rapid preequilibrium in which the catal

Full text of DOI:10.1016/0040-4020(80)88025-2

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