Diastereoselectivity of the thio-Claisen rearrangement of acyclic precursors bearing a chiral centre adjacent to carbon 6

DOI: 10.1016/S0040-4020(01)88337-X

Source and publish data:

Tetrahedron p. 10327 - 10338 (1992)

Update date:2022-09-26

Topics:

Authors:

Desert, Stephane

Metzner, Patrick

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)88337-X

A number of chiral allylic alcohols have been prepared and submitted to a Mitsunobu reaction with dithioacetic acid. Allyl dithioesters were deprotonated by LDA at -30°C and resulting enethiolates were quenched with iodomethane to afford quantitatively S-

Full text of DOI:10.1016/S0040-4020(01)88337-X

Products guided by the article

Product name:(E)-(S)-4-phenylmethoxy-2-pentenyl ethanedithioate

Cas No:147189-66-0

R&D Labs maybe for 147189-66-0

Acorn PharmaTech Co., Ltd

Contact:86-25-58619180

Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.

website:http://www.sino-strong.com.cn

Contact:+86-28-82666753

Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China

Relevant to this article

On the Reaction of α-Chlorobenzylic Cations with Isocyanates

Doi:10.1002/prac.19923340804
(1992)
Self-addition products from the alkylation of amino acid-derived oxazolidinones: X-ray molecular structures of (2R,4S,1′S)-3-benzoyl-4-[benzoylamino(phenyl)methyl]-4-benzyl-2-phenyl-1, 3-oxazolidin-5-one, (2A,45,1′S)- and (2R,4S,1′R)-3-benzoyl-4-[benzoylamino(phenyl)methyl]-4-isopropyl-2-phenyl- 1,3-oxazolidin-5-one

Doi:10.1039/P19960001299
(1996)
Curtius rearrangement of aromatic carboxylic acids to access protected anilines and aromatic ureas

Doi:10.1021/ol0622920
(2006)
Doi:10.1021/jo01266a074
(1968)
'Inverse Cryptate' Structure of an Exceptionally Stable Dicopper(I) Semiquinonoid Intermediate

Doi:10.1039/DT9930000211
(1993)
New process for the synthesis of UP 269-6, a 1,2,4-triazolo[1,5-c]pyrimidine derivative as a potent orally active angiotensin II antagonist

Doi:10.1002/jhet.5570330450
(1996)

Article Doi