Diastereoselectivity of the thio-Claisen rearrangement of acyclic precursors bearing a chiral centre adjacent to carbon 6

DOI: 10.1016/S0040-4020(01)88337-X

Source and publish data:

Tetrahedron p. 10327 - 10338 (1992)

Update date:2022-09-26

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Authors:

Desert, Stephane

Metzner, Patrick

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Article abstract of DOI:10.1016/S0040-4020(01)88337-X

A number of chiral allylic alcohols have been prepared and submitted to a Mitsunobu reaction with dithioacetic acid. Allyl dithioesters were deprotonated by LDA at -30°C and resulting enethiolates were quenched with iodomethane to afford quantitatively S-

Full text of DOI:10.1016/S0040-4020(01)88337-X

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