B-C bond formation by ene-type reactions of dimethylaminobis(trifluoromethyl)borane with nitriles and carbonyl compounds. Crystal structure of (NCCH2)(CF3)2B*NHMe2

DOI: 10.1016/0022-328X(93)83046-X

Source and publish data:

Journal of Organometallic Chemistry p. 5 - 14 (1993)

Update date:2022-08-04

Topics:

Authors:

Ansorge, A.

Brauer, D.J.

Buerger, H.

Hagen, T.

Pawelke, G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(93)83046-X

Dimethylaminobis(trifluoromethyl)borane, (CF3)2BNMe2 (A), reacts with nitriles RCH2-C<*>N<*> to yield triorganoboron adducts (<*>N<*>C-CHR)(CF3)2B * NHMe2 (R = H (I), Cl(II), Me(III) and Et(IV)).Analogously carbonyl compounds of the general formula R

Full text of DOI:10.1016/0022-328X(93)83046-X

Products guided by the article

Product name:phenylcarbonylmethyl-bis(trifluoromethyl)borane-dimethylamine

Cas No:148272-40-6

R&D Labs maybe for 148272-40-6

Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
ZHEJIANG NHU COMPANY LTD.

Contact:86-575-86132822，86-575-86085355

Address:No.418 Dadao West Road,Qixing Street,Xinchang, Zhejiang Province, China.
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China

Relevant to this article

Highly Enantioselective Synthesis of Propargyl Alcohols

Doi:10.1016/S0040-4039(00)60315-5
(1993)
Enantio- and Diastereoisomers of 2,4-Dimethoxy-5-(2,3-dideoxy-5-O-tritylribofuranosyl)pyrimidine. 2',3'-Dideoxy Pyrimidine C-Nucleosides by Palladium-Mediated Glycal-Aglycon Coupling

Doi:10.1021/jo00061a034
(1993)
Synthesis of novel imidazo[1,2-a]pyrimidin-5(1H)-one derivatives by intramolecular cycloisomerization of 2-amino-3-alkynylpyrimidin-4(3H)-one in the presence of aqueous base

Doi:10.1246/cl.130454
(2013)
The synthesis of N,N-Bis(dialkoxyphosphinoylmethyl)- and N,N-Bis(diphenylphosphinoylmethyl)glycine esters by the microwave-assisted double kabachnik-fields reaction

Doi:10.1002/hc.21126
(2013)
Encapsulation of copper(I)-Schiff base complex in NaY nanoporosity: An efficient and reusable catalyst in the synthesis of propargylamines via A ³-coupling (aldehyde-amine-alkyne) reactions

Doi:10.1016/j.apcata.2013.03.008
(2013)
A facile chemoenzymatic route to enantiomerically pure 4,5-disubstituted-2-hexenoae derivatives

Doi:10.1248/cpb.39.3094
(1991)

Article Doi