B-C bond formation by ene-type reactions of dimethylaminobis(trifluoromethyl)borane with nitriles and carbonyl compounds. Crystal structure of (NCCH2)(CF3)2B*NHMe2

DOI: 10.1016/0022-328X(93)83046-X

Source and publish data:

Journal of Organometallic Chemistry p. 5 - 14 (1993)

Update date:2022-08-04

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Authors:

Ansorge, A.

Brauer, D.J.

Buerger, H.

Hagen, T.

Pawelke, G.

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Article abstract of DOI:10.1016/0022-328X(93)83046-X

Dimethylaminobis(trifluoromethyl)borane, (CF3)2BNMe2 (A), reacts with nitriles RCH2-C<*>N<*> to yield triorganoboron adducts (<*>N<*>C-CHR)(CF3)2B * NHMe2 (R = H (I), Cl(II), Me(III) and Et(IV)).Analogously carbonyl compounds of the general formula R

Full text of DOI:10.1016/0022-328X(93)83046-X

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