B-C bond formation by ene-type reactions of dimethylaminobis(trifluoromethyl)borane with nitriles and carbonyl compounds. Crystal structure of (NCCH2)(CF3)2B*NHMe2

DOI: 10.1016/0022-328X(93)83046-X

Source and publish data:

Journal of Organometallic Chemistry p. 5 - 14 (1993)

Update date:2022-08-04

Topics:

Authors:

Ansorge, A.

Brauer, D.J.

Buerger, H.

Hagen, T.

Pawelke, G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(93)83046-X

Dimethylaminobis(trifluoromethyl)borane, (CF3)2BNMe2 (A), reacts with nitriles RCH2-C<*>N<*> to yield triorganoboron adducts (<*>N<*>C-CHR)(CF3)2B * NHMe2 (R = H (I), Cl(II), Me(III) and Et(IV)).Analogously carbonyl compounds of the general formula R

Full text of DOI:10.1016/0022-328X(93)83046-X

Products guided by the article

Product name:phenylcarbonylmethyl-bis(trifluoromethyl)borane-dimethylamine

Cas No:148272-40-6

R&D Labs maybe for 148272-40-6

Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
WUXI HONOR SHINE CHEMICAL CO.,LTD

Contact:+86-510-83593312

Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727

Relevant to this article

Highly Enantioselective Synthesis of Propargyl Alcohols

Doi:10.1016/S0040-4039(00)60315-5
(1993)
Enantio- and Diastereoisomers of 2,4-Dimethoxy-5-(2,3-dideoxy-5-O-tritylribofuranosyl)pyrimidine. 2',3'-Dideoxy Pyrimidine C-Nucleosides by Palladium-Mediated Glycal-Aglycon Coupling

Doi:10.1021/jo00061a034
(1993)
Synthesis of novel imidazo[1,2-a]pyrimidin-5(1H)-one derivatives by intramolecular cycloisomerization of 2-amino-3-alkynylpyrimidin-4(3H)-one in the presence of aqueous base

Doi:10.1246/cl.130454
(2013)
The synthesis of N,N-Bis(dialkoxyphosphinoylmethyl)- and N,N-Bis(diphenylphosphinoylmethyl)glycine esters by the microwave-assisted double kabachnik-fields reaction

Doi:10.1002/hc.21126
(2013)
Encapsulation of copper(I)-Schiff base complex in NaY nanoporosity: An efficient and reusable catalyst in the synthesis of propargylamines via A ³-coupling (aldehyde-amine-alkyne) reactions

Doi:10.1016/j.apcata.2013.03.008
(2013)
A facile chemoenzymatic route to enantiomerically pure 4,5-disubstituted-2-hexenoae derivatives

Doi:10.1248/cpb.39.3094
(1991)

Article Doi