An improved procedure for aldehyde-to-alkyne homologation via 1,1-dibromoalkenes: Synthesis of 1-bromoalkynes

DOI: 10.1016/S0040-4039(00)73227-8

Source and publish data:

Tetrahedron Letters p. 3529 - 3530 (1994)

Update date:2022-07-30

Topics: Synthesis Aldehyde Alkyne Experimental procedure Homologation 1,1-dibromoalkenes

Authors:

Grandjean

Pale Pale

Chuche Chuche

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73227-8

1,1-Dibromoalkenes, 1-bromoalkynes and alkynes could be obtained in excellent yields by homologation of functionalized aldehydes through a modified Mc Kelvie-Corey procedure.

Full text of DOI:10.1016/S0040-4039(00)73227-8

Products guided by the article

Product name:tert-Butyl-[2-(2,2-dibromo-vinyl)-cyclopropylmethoxy]-diphenyl-silane

Cas No:157399-07-0

R&D Labs maybe for 157399-07-0

SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Shanghai WinTide BioTechnology Co.,Ltd

Contact:86-21-37100630

Address:No. 908 Yunhe Road, Fengxian district, Shanghai
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.

Relevant to this article

Doi:10.1021/ja01579a036
(1957)
Doi:10.1016/S0040-4020(01)92357-9
(1981)
Exploring the scope of [Pt₂(4-FC₆H₄) ₄(μ-SEt₂)₂] as a precursor for new organometallic platinum(II) and platinum(IV) antitumor agents

Doi:10.1021/om5000908
(2014)
Ligand-field Control in the Self-assembly of Polymeric Metal Complexes: Copper(II) Complexes with Quadridentate Schiff-base Ligands involving an Imidazole Moiety

Doi:10.1039/DT9940002339
(1994)
Oligosaccharides and peptide displayed on an amphiphilic polymer enable solid phase assay of hapten specific antibodies

Doi:10.1021/bc400486w
(2014)
Divergent palladium iodide catalyzed multicomponent carbonylative approaches to functionalized isoindolinone and isobenzofuranimine derivatives

Doi:10.1021/jo500281h
(2014)

Article Doi