A Novel Asymmetric Desymmetrisation of meso-Cyclopentane-1,2-diol via Diastereoselective β-Elimination of Chiral α-Arylsulfinyl Acetals

DOI: 10.1039/c39940001345

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Journal of the Chemical Society. Chemical communications p. 1345 - 1346 (1994)

Update date:2022-08-02

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Authors:

Maezaki, Naoyoshi

Soejima, Motohiro

Takeda, Miwako

Sakamoto, Atsunobu

Tanaka, Tetsuaki

Iwata, Chuzo

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Article abstract of DOI:10.1039/c39940001345

meso-Cyclopentane-1,2-diol was differentiated via diastereoselective C-O bond fission of the acetal utilising the anion stabilised by a neighbouring chiral sulfinyl group to provide the chiral alcohol.

Full text of DOI:10.1039/c39940001345

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