Epoxides Derived from Pyranosyl Dienes: Unusually Stable Glycosyl Donors

DOI: 10.1016/0040-4039(94)88445-5

Source and publish data:

Tetrahedron Letters p. 9131 - 9134 (1994)

Update date:2022-08-02

Topics: Stability Experimental Epoxides Glycosyl donors

Authors:

Link, J. T.

Danishefsky, Samuel J.

Schulte, Gayle

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Article abstract of DOI:10.1016/0040-4039(94)88445-5

A pyranosyl diene appropriately substituted for use in a total synthesis of staurosporine has been synthesized.The mono-epoxides and bis-epoxides obtained from treatment of this diene with dimethyldioxirane are unusually stable.

Full text of DOI:10.1016/0040-4039(94)88445-5

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