
Tetrahedron Letters p. 9131 - 9134 (1994)
Update date:2022-08-02
Topics: Stability Experimental Epoxides Glycosyl donors
Link, J. T.
Danishefsky, Samuel J.
Schulte, Gayle
A pyranosyl diene appropriately substituted for use in a total synthesis of staurosporine has been synthesized.The mono-epoxides and bis-epoxides obtained from treatment of this diene with dimethyldioxirane are unusually stable.
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