Stereoselective Formation of Three Carbon-Carbon Bonds by Cascade Reaction with Enolate Anion: Synthesis of Tricyclo1,6>dodecane and Tricyclo3,8>undecane Derivatives

DOI: 10.1021/jo00099a034

Source and publish data:

Journal of Organic Chemistry p. 6008 - 6013 (1994)

Update date:2022-09-26

Topics: Synthesis Derivatives Cascade reaction Stereoselective

Authors:

Ihara, Masataka

Makita, Kei

Tokunaga, Yuji

Fukumoto, Keiichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00099a034

Reaction of 6-<5(E)-6-(methoxycarbonyl)hex-5-enyl>-2-cyclohexen-1-one (1) with LHMDS, followed by one-pot treatment with CH2O, resulted in a cascade Michael-Michael-aldol reaction, producing hydroxymethylated tricyclo<6.2.2.0^1,6>dodecane 3.The

Full text of DOI:10.1021/jo00099a034

Products guided by the article

Product name:5-<3-(1,3-Dioxacyclohexyl)propyl>-2-methylcyclohexan-1-one

Cas No:165316-61-0

R&D Labs maybe for 165316-61-0

SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Hangzhou Deli Chemical Co.,Ltd.

website:http://www.dlchemical.com

Contact:86 571 28006267

Address:Tangxi Industrial Area, Yuhang District, Hangzhou
Shanghai Witshoot Internet Technology Co Ltd

Contact:+86-21-66390020

Address:Room 419, No.285 Luochuan Road (E)
HEZE KINGVOLT CHEMICAL CO., LTD

Contact:86-573-82118911

Address:Juancheng Industry Park

Relevant to this article

Carbazol derivatives with antimycobacterial activity

Doi:10.1002/ardp.19943271003
(1994)
Ligand interactions with E-selectin. Identification of a new binding site for recognition of N-acyl aromatic glucosamine substituents of sialyl Lewis X

Doi:10.1021/jm9600611
(1996)
Facile N-arylation of amines and sulfonamides and O-arylation of phenols and arenecarboxylic acids

Doi:10.1021/jo0602221
(2006)
Synthesis, binding properties and theoretical studies of p-tert-butylhexahomotrioxacalix[3]arene tri(adamantyl)ketone with alkali, alkaline earth, transition, heavy metal and lanthanide cations

Doi:10.1016/j.tet.2008.11.005
(2009)
Double Arbuzov Reaction of in Situ Generated Bis(trimethylsiloxy)phosphine with Dielectrophiles: Methodology for the Synthesis of Cyclic Phosphinic Acids

Doi:10.1021/jo00124a018
(1995)
Perhalogenated porphyrinic derivatives with indium and thallium: The X-ray structures of (β-Cl₄TPP)Tl(Cl), (β-Cl₄TPP)In(Cl) and (TpFTPP)Tl(Cl)

Doi:10.1016/j.poly.2004.04.010
(2004)

Article Doi