Toluene-dioxygenase-mediated cis-dihydroxylation of aromatics in enantioselective synthesis. Iterative glycoconjugate coupling strategy and combinatorial design for the synthesis of oligomers of nor-saccharides, inositols and pseudosugars with interesting

Article abstract of DOI:10.1055/s-1996-4440

Vinyl epoxides 18 and 31 and vinylaziridines 24 and 25 derived from chloro- or bromocyclohexadiene-cis-diols 9 have been condensed with protected cyclitols 19, 37, and 46 in an iterative manner to generate dimeric, trimeric and tetrameric conduritol or am