Stepwise insertion of alkylisocyanides into the metal-alkyne bond of half-sandwich type rhodium complexes: Synthesis and structural characterization of metallacyclobutenes and metallacyclopentenes

DOI: 10.1002/cber.19961290805

Source and publish data:

Chemische Berichte p. 903 - 910 (1996)

Update date:2022-09-26

Topics:

Authors:

Werner, Helmut

Heinemann, Anja

Windmueller, Bettina

Steinert, Paul

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Article abstract of DOI:10.1002/cber.19961290805

The cyclopentadieny! complexes [C₅H₅Rh(RC=CR′)(SbiPr₃)] (5-8), which were prepared from frans-[RhCl(RC=CR′)(SbJPr₃)₂] (1-4) and NaC₅H₅ and which contain a labile Rh-SbiPr_{3
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Full text of DOI:10.1002/cber.19961290805

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Product name:[Rh(CO)(C₅H₅)(C₆H₅CCC₆H₅)]

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