Rational design of Mn-salen catalyst (2): Highly enantioselective epoxidation of conjugated cis-olefins

DOI: 10.1016/S0040-4020(01)89298-X

Source and publish data:

Tetrahedron p. 11827 - 11838 (1994)

Update date:2022-07-30

Topics:

Authors:

Sasaki Sasaki

Irie Irie

Hamada Hamada

Suzuki Suzuki

Katsuki Katsuki

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Article abstract of DOI:10.1016/S0040-4020(01)89298-X

On the basis of the newly proposed hypothesis on the mechanism of asymmetric induction, highly efficient (salen)mangenese(III) complex (3) was constructed as a catalyst for asymmetric epoxidation. With this catalyst, the highest level of enantioselectivit

Full text of DOI:10.1016/S0040-4020(01)89298-X

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