(Benzenethiolato-S)(4-tert-butylpyridine-N)bis(dimethylglyoximato-N,N') cobalt(III) and (4-tert-butylpyridine-N)bis(dimethylglyoximato-N,N')(4-methoxybenzenethiolato-S) cobalt(III)

DOI: 10.1107/S0108270198001693

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 945 - 947 (1998)

Update date:2022-07-30

Topics:

Authors:

Inouye, Yoshinobu

Kambe, Tohru

Tada, Masaru

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Article abstract of DOI:10.1107/S0108270198001693

The Co-S distances in the title compounds, [Co-(C₄H₇N₂O₂)₂(C ₉H₁₃N)(C₆H₅S)] and [Co(C₄H₇N₂O₂)2-(C₉H ₁₃N)(C₇H₇OS)], are 2.2800 (8) and 2.2885 (15) A, respectively. The electron-donating substituent on the para position of the arylthiolate lengthens the Co-S bond.

Full text of DOI:10.1107/S0108270198001693

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