Tetrahedron Letters p. 6733 - 6736 (1998)
Update date:2022-08-05
Topics:
Gibson, Colin L.
Gillon, Karen
Cook, Stuart
A series of three 5,5-diaryl substituted oxazolidin-2-ones (diphenyl, dinaphthyl and ditolyl) have been prepared and shown to be particularly effective chiral auxiliaries to afford high yields and diastereoselectivities for alkylation and azidations of their N-acyl derivatives. The 5,5-ditolyl oxazolidin-2-one proved to be particularly efficacious in terms of diastereoselectivity, yield and solubility.
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(1998)