Reaction of Zirconocene Ethylene Complex with Diynes. Formation of Bridged Zirconacyclopentenes

DOI: 10.1246/cl.1995.347

Source and publish data:

Chemistry Letters p. 347 - 348 (1995)

Update date:2022-08-02

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Authors:

Takahashi, Tamotsu

Kasai, Kayoko

Xi, Zhenfeng

Denisov, Victor

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Article abstract of DOI:10.1246/cl.1995.347

Reactions of diynes RCC-X-CCR with zirconocene ethylene complex Cp2Zr(CH2=CH2) were investigated.When X was C6H4 or C4H2S bridged zirconacyclopentenes were selectively formed.They were easily converted into bridged cyclopentenone derivatives.In the case o

Full text of DOI:10.1246/cl.1995.347

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