Synthesis of a novel heterocyclic dioxime and its mononuclear complexes with Ni(II), Co(II), Cu(II), Zn(II), Cd(II) and Hg(II)

Article abstract of DOI:10.1080/00945719909349466

In this work, a novel heterocyclic dioxime (2,3-hydroximino-4-phenyl-6-phenlyazo-1-thia-4,5-diazacyclohexa-5-diene, H₂L) was synthesized by reacting dithizone with cyanogen di-N-oxide. H₂L forms mononuclear complexes [(HL)₂M] with a metal-ligand ratio of 1:2 with M = Ni(II), Co(II) and Cu(II). Zn(II), Cd(II) and Hg(II) form with H₂L complexes [(HL)Cl(H₂O)M] which have a metal-ligand ratio of 1:1 and contain a six-membered chelate ring. Structures of these compounds are proposed based on elemental analyses, U.V.-Visible, IR, ¹H NMR, mass spectra and magnetic susceptibility measurements.

Full text of DOI:10.1080/00945719909349466

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Synthesis and Reactivity in
Inorganic and Metal-Organic
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Synthesis of a Novel
Heterocyclic Dioxime and Its
Mononuclear Complexes with
Ni(II), Co(II), Cn(II), Zn(II), Cd(II)
and Hg(II)
Bedrettin Mercimek a , M. Ali Bzler a , Gazi Ira a &
Özer Bekaroĝlu b
a Department of Chemistry, Faculp of Arts and
Sciences , Mugla University , 48000, Muĝla, Turkey
b Department of Chemistry , Technical University of
Istanbul , Maslak, Istanbul, Turkey
Published online: 14 Apr 2008.
To cite this article: Bedrettin Mercimek , M. Ali Bzler , Gazi Ira & Özer Bekaroĝlu
(1999) Synthesis of a Novel Heterocyclic Dioxime and Its Mononuclear Complexes with
Ni(II), Co(II), Cn(II), Zn(II), Cd(II) and Hg(II), Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 29:3, 513-524, DOI: 10.1080/00945719909349466
To link to this article: http://dx.doi.org/10.1080/00945719909349466
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