Reformatsky-type addition of esters of α-halogeno carboxylic acids to aldehydes and ketones in the presence of Fe(CO)5

DOI: 10.1007/BF02496013

Source and publish data:

Russian Chemical Bulletin p. 1121 - 1127 (1999)

Update date:2022-08-03

Topics:

Authors:

Terent'ev

Vasil'eva

Kuz'mina

Mysov Mysov

Ikonnikov

Kuznetsov

Belokon'

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Article abstract of DOI:10.1007/BF02496013

Reformatsky-type addition of esters of α-halogeno carboxylic acids to aldehydes and ketones in the presence of Fe(CO)₅ and an activating agent (CBrCl₃ or I₂) afforded the corresponding esters of β-hydroxy acids in good yields. Possible reaction mechanisms are discussed.

Full text of DOI:10.1007/BF02496013

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