Journal of the American Chemical Society p. 1668 - 1674 (2017)
Update date:2022-08-04
Topics:
Toutov, Anton A.
Betz, Kerry N.
Schuman, David P.
Liu, Wen-Bo
Fedorov, Alexey
Stoltz, Brian M.
Grubbs, Robert H.
Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C-H bond functionalization protocol for the construction of C(sp)-Si bonds in a single step. The scope of the alkyne and hydrosilane partners is substantial, providing an entry point into various organosilane building blocks and additionally enabling the discovery of a number of novel synthetic strategies. Remarkably, the optimal catalysts are NaOH and KOH.
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