Helvetica Chimica Acta p. 2598 - 2602 (1982)
Update date:2022-09-26
Topics:
Seebach, Dieter
Schiess, Martin
The readily available tris(diethylamino)methyltitanium and related compounds (see 1 in Scheme 2) react with non-enolizable aldehydes to give tertiary amines 2; these amines result from direct replacement of the carbonyl O-atom by an alkyl and an amino group (Scheme 3).A tentative mechanism is proposed, according to which the amino group is transferred to the carbonyl C-atom prior to the alkyl group (Scheme 4).
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Doi:10.1002/jps.2600640214
(1975)Doi:10.1016/j.ejmech.2012.09.037
(2012)Doi:10.1021/ja01103a519
(1953)Doi:10.1039/c39850001390
(1985)Doi:10.1021/jo00902a010
(1975)Doi:10.1021/ja039218m
(2004)
