Helvetica Chimica Acta p. 2598 - 2602 (1982)
Update date:2022-09-26
Topics:
Seebach, Dieter
Schiess, Martin
The readily available tris(diethylamino)methyltitanium and related compounds (see 1 in Scheme 2) react with non-enolizable aldehydes to give tertiary amines 2; these amines result from direct replacement of the carbonyl O-atom by an alkyl and an amino group (Scheme 3).A tentative mechanism is proposed, according to which the amino group is transferred to the carbonyl C-atom prior to the alkyl group (Scheme 4).
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