
Journal of Organometallic Chemistry p. 239 - 256 (1982)
Update date:2022-08-04
Topics:
Daub, Joerg
Kappler, Joachim
Jogun, Kurt H.
Stezowski, John J.
Binder, Herbert
The pentacarbonyl thionocarbonate metal complexes III, IV, and V are synthesized under photochemical conditions from Cr(CO)6, Mo(CO)6, W(CO)6, and thionocarbonates I in THF.Reactions of the new complexes are described, and spectroscopic properties (IR, NMR, MS, and ESCA) discussed.The crystal structure of IIIa was determined by single crystal X-ray techniques.
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