Synthesis of 3-amino-3-vinylpropanoic acid and its conversion to 4-amino-5-hydroxy-4,5-dihydrofuran-2-one hydrochloride (HAD), a cyclic stabilised form of aspartate 1-semialdehyde hydrochloride

DOI: 10.1016/S0040-4020(97)10033-3

Source and publish data:

Tetrahedron p. 15807 - 15812 (1997)

Update date:2022-08-05

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Authors:

Cheung, Kwai-Ming

Shoolingin-Jordan, Peter M.

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Article abstract of DOI:10.1016/S0040-4020(97)10033-3

3-amino-3-vinylpropanoic acid hydrochloride 4 was obtained from 4-acetoxyazetidin-2-one 1 in 3 steps. The ozonolysis of 4 yielded 3-amino-4-oxopropanoic acid hydrochloride (aspartate 1-semialdehyde hydrochloride 6). This labile α-aminoaldehyde is isolated

Full text of DOI:10.1016/S0040-4020(97)10033-3

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