Tetrahedron p. 7793 - 7802 (1993)
Update date:2022-08-03
Topics:
Versleijen
Sanders-Hovens
Vanhommerig
Vekemans
Meijer
The scope and mechanism of enantioselective hydride transfer from NADH model 4 to prochiral C=O and C=N compounds were investigated. Efficient chirality transfer from 4 to α-keto esters and α-methoxycarbonylimino esters was achieved. The resemblance in reactivity and stereochemistry of the prochiral C=O and C=N-CO2Me functionalities in the hydride transfer reaction is attributed to the intervention of a similar Mg(ClO4)2-mediated ternary complex.
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Doi:10.1016/S0040-4020(01)80939-X
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(1983)
