Asymmetric Synthesis of (-)-3β-Hydroxy-17-methoxy-D-homo-18-nor-5α-androsta-13,15,17-triene

DOI: 10.1021/jo01299a033

Source and publish data:

Journal of Organic Chemistry p. 2204 - 2207 (1980)

Update date:2022-07-30

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Authors:

Kametani, Tetsuji

Suzuki, Koji

Nemoto, Hideo

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Article abstract of DOI:10.1021/jo01299a033

A stereoselective synthesis of (-)-3β-hydroxy-17-methoxy-D-homo-18-nor-5α-androsta-13,15,17-triene (2), an important intermediate in the synthesis of 20-oxo-5α-Δ¹⁶-pregnen-3β-ol acetate (3), has been achieved by thermolysis of optically active

Full text of DOI:10.1021/jo01299a033

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