Frontier-Controlled Pericyclic Reaction of Phencyclone with 1H-Azepine. Remarkably Accelerated Aromatic Cope Rearrangement of an Endo--? Cycloadduct

DOI: 10.1021/jo01300a021

Source and publish data:

Journal of Organic Chemistry p. 2368 - 2372 (1980)

Update date:2022-07-31

Topics:

Authors:

Yasuda, Masami

Harano, Kazunobu

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01300a021

The endo-<4+2>-? cycloadducts of phencyclone derivatives and N-(ethoxycarbonyl)azepine were isolated and readily isomerized to anti-endo-<2+4>-? cycloadducts.The kinetics of the rearrangement of endo-<4+2>-? cycloadducts have been examined.The aromatic Co

Full text of DOI:10.1021/jo01300a021

Products guided by the article

Product name:C₃₈H₂₉NO₃

Cas No:73333-41-2

R&D Labs maybe for 73333-41-2

Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong

Relevant to this article

Synthesis of 6-amino-1,2,3-triazolo[4,5-c]pyridin-4(5H)one (8-aza-3-deazaguanine) and 6-amino-1-(β-D-ribofuranosyl)-1,2,3-triazolo[4,5-c]pyridin-4(5H)one (8-aza-3-deazaguanosine) via novel ring closure procedures

Doi:10.1002/jhet.5570170132
(1980)
Borazine materials for organic optoelectronic applications

Doi:10.1039/b504510j
(2005)
Unexpected formation of aryl ketones by palladium-catalyzed coupling of aryl bromides with vinylic acetates

Doi:10.1021/ol7015065
(2007)
Doi:10.1016/S0040-4039(01)86596-5
(1979)
8-Oxabicyclo[3.2.1]octanes: Synthesis and structure of the four diastereomeric 8-oxacocaines

Doi:10.1002/ardp.19903230402
(1990)
Studies of the Generation of Excited Singlet Products in the Oxidation of the -CO-CH- Containing Molecules. The Chemiluminescence of Acylcarbazoles

Doi:10.1246/bcsj.54.25
(1981)

Article Doi