Frontier-Controlled Pericyclic Reaction of Phencyclone with 1H-Azepine. Remarkably Accelerated Aromatic Cope Rearrangement of an Endo--? Cycloadduct

DOI: 10.1021/jo01300a021

Source and publish data:

Journal of Organic Chemistry p. 2368 - 2372 (1980)

Update date:2022-07-31

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Authors:

Yasuda, Masami

Harano, Kazunobu

Kanematsu, Ken

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Article abstract of DOI:10.1021/jo01300a021

The endo-<4+2>-? cycloadducts of phencyclone derivatives and N-(ethoxycarbonyl)azepine were isolated and readily isomerized to anti-endo-<2+4>-? cycloadducts.The kinetics of the rearrangement of endo-<4+2>-? cycloadducts have been examined.The aromatic Co

Full text of DOI:10.1021/jo01300a021

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