Thio-Claisen and Cope Rearrangements. A General Method for the Synthesis of α,β,ε,ζ-Unsaturated Thioamides

Article abstract of DOI:10.1021/ja00527a043

Thio-Claisen rearrangement (α-allylation of α,β-unsaturated thioamides giving α-allylated β,γ-unsaturated thioamides 4) followed by Cope rearrangement has provided a new method for the preparation of α,β,ε,ζ-unsaturated thioamides 9.A series of α-allylate