Tetrahedron Letters p. 1993 - 1996 (1988)
Update date:2022-09-26
Topics:
Cox, Paul
Mahon, Mary F.
Molloy, Kieran C.
Lister, Simon
Gallagher, Timothy
The synthesis of 6-lithio-5-methoxy-3,4-dihydro-2H-pyran (6) and its use as a regiospecific ketone enolate equivalent is described for the first time.This anion has been used to prepare the bicyclic hemiketal (5), a synthetic model for herbicidin B (1).
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