Tetrahedron Letters p. 1993 - 1996 (1988)
Update date:2022-09-26
Topics:
Cox, Paul
Mahon, Mary F.
Molloy, Kieran C.
Lister, Simon
Gallagher, Timothy
The synthesis of 6-lithio-5-methoxy-3,4-dihydro-2H-pyran (6) and its use as a regiospecific ketone enolate equivalent is described for the first time.This anion has been used to prepare the bicyclic hemiketal (5), a synthetic model for herbicidin B (1).
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Doi:10.1016/S0008-6215(00)85932-7
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(2001)Doi:10.1080/00397910701411044
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(1981)Doi:10.1016/j.tetlet.2005.10.144
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(1981)
