Helvetica Chimica Acta p. 357 - 361 (1981)
Update date:2022-08-02
Topics:
Weidmann, Beat
Widler, Leo
Olivero, Alan G.
Maycock, Christopher D.
Seebach, Dieter
Solutions of the title compounds R-Ti(OR')3 (1) are generally available from organolithium (or magnesium) derivatives according to equation 1.It is shown (table 1) that some heterosubstituted organotitanium compounds are more stable thermally than their lithium counterparts.The reagents 1 are highly selective carbonylophiles (Tables 1 and 2), their reactivity can be modified by variation of the R'O-group (Table 3) and with the chiral (S)-2-methyl-1-butoxy group an enantioselective addition can be achieved.
View MoreHangzhou innopharma technology Co,.Ltd.(expird)
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
Shanghai Dynamic Industrial Co.,Ltd.
website:http://www.shdynamic.com
Contact:86-021 3392 6680
Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.
Contact:+86-0799-3413066
Address:Xiyuan village, Xiabu Town, Xiangdong District
Contact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
Hubei Xinjing New Material Co.,Ltd
Contact:+86-27-83313147
Address:Room402.#Bthe 7th,Headquarter of Huifeng Corporation Qiaokou District,Wuhan China
Doi:10.1021/jm00141a010
(1981)Doi:10.1002/ejoc.200600123
(2006)Doi:10.1021/jm100697g
(2010)Doi:10.1002/ejoc.201600051
(2016)Doi:10.1016/S0272-6386(05)80003-4
(1944)Doi:10.1021/jo00333a021
(1981)