Helvetica Chimica Acta p. 357 - 361 (1981)
Update date:2022-08-02
Topics:
Weidmann, Beat
Widler, Leo
Olivero, Alan G.
Maycock, Christopher D.
Seebach, Dieter
Solutions of the title compounds R-Ti(OR')3 (1) are generally available from organolithium (or magnesium) derivatives according to equation 1.It is shown (table 1) that some heterosubstituted organotitanium compounds are more stable thermally than their lithium counterparts.The reagents 1 are highly selective carbonylophiles (Tables 1 and 2), their reactivity can be modified by variation of the R'O-group (Table 3) and with the chiral (S)-2-methyl-1-butoxy group an enantioselective addition can be achieved.
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Doi:10.1021/jm00141a010
(1981)Doi:10.1002/ejoc.200600123
(2006)Doi:10.1021/jm100697g
(2010)Doi:10.1002/ejoc.201600051
(2016)Doi:10.1016/S0272-6386(05)80003-4
(1944)Doi:10.1021/jo00333a021
(1981)
