SYNTHETIC STUDIES ON TERPENOIDS-III SYNTHETIC APPROACHES TO DITERPENE ALKALOIDS

DOI: 10.1016/S0040-4020(01)92341-5

Source and publish data:

Tetrahedron p. 2749 - 2753 (1981)

Update date:2022-09-26

Topics:

Authors:

Banerjee, Ajoy K.

Caraballo, Pedro C.

Hurtado, Hector S.

Carrasco, Maria C.

Rivas, Carlos

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Article abstract of DOI:10.1016/S0040-4020(01)92341-5

A stereoselective synthetic route to the bicyclic keto ester 14 from octalin 4 is described.Ketoester 14 is converted to its azide 27 in several steps.Photolysis of 27 produced the lactam 2 whose transformation to lactam 3 is reported.

Full text of DOI:10.1016/S0040-4020(01)92341-5

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