Low-Temperature and Time-Resolved Absorption Spectral Studies on the sp- and ap-2-(9-Fluorenyl)phenylnitrenes Generated from 1-Azatriptycene and 2-(9-Fluorenyl)phenyl Azide

DOI: 10.1021/ja00342a036

Source and publish data:

Journal of the American Chemical Society p. 858 - 862 (1983)

Update date:2022-07-30

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Authors:

Sugawara, Tadashi

Nakashima, Nobuaki

Yoshihara, Keitaro

Iwamura, Hiizu

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Article abstract of DOI:10.1021/ja00342a036

Mechanistic details of the photorearrangement of 1-azatriptycene (1) have been disclosed by absorption spectroscopic studies on the irradiation of 1 and o- and p-(9-fluorenyl)phenyl azides (3 and 4).At 77 K, 1 developed on irradiation absorption peaks at

Full text of DOI:10.1021/ja00342a036

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