Palladium-Catalyzed Allylic Oxidation of Cyclohexenes Using Molecular Oxygen as Oxidant

DOI: 10.1021/jo00309a005

Source and publish data:

Journal of Organic Chemistry p. 5674 - 5675 (1990)

Update date:2022-09-26

Topics:

Authors:

Bystroem, Styrbjoern E.

Larsson, E. Magnus

Akermark, Bjoern

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Article abstract of DOI:10.1021/jo00309a005

Cyclohexene and some related alkenes are readily converted into allyl acetates by catalytic amounts of palladium acetate and a reoxidation system consisting of molecular oxygen and either hydroquinone and a second transition metal acetate or cobalt(II) Schiff's base complexes such as 7 and 8.

Full text of DOI:10.1021/jo00309a005

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