Tetrahedron Letters p. 4181 - 4184 (1988)
Update date:2022-08-02
Topics:
Pelter, Andrew
Drake, Robert A.
It is shown that the methyl group cannot be used as a cheap, non-migrating group in the reactions of alkynyltrialkylborates with electrophiles.However, trimethylborane can be used as a methylboronating agent for alkynes, given the right choice of solvent, and this may be of use in terpene synthesis.
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