NEW ATROPISOMERIC CHIRAL BISPHOSPHINE, (S)-6,6'-DIMETHYL-2,2'-BIS(DIPHENYLPHOSPHINAMINO)BIPHENYL, AND ASYMMETRIC HYDROGENATION USING THE Rh(I) COMPLEX THEREOF

DOI: 10.1246/cl.1983.441

Source and publish data:

Chemistry Letters p. 441 - 444 (1983)

Update date:2022-08-04

Topics:

Authors:

Uehara, Akira

Kubota, Tohru

Tsuchiya, Ryokichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1983.441

Atropisomeric chiral bisphosphine, (S)-6,6'-dimethyl-2,2'-bis(diphenylphosphinamino)biphenyl (MABP) was newly prepared, and the Rh(I) complex thereof was found to be highly effective for the asymmetric hydrogenation of 2-acetamidoacrylic acid even under 1 atm of hydrogen pressure at a temperature below 0 deg C.

Full text of DOI:10.1246/cl.1983.441

Products guided by the article

Product name:(Ra)-6,6'-dimethyl-1,1'-biphenyl-2,2'-diamine

Cas No:86560-87-4

R&D Labs maybe for 86560-87-4

JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)

Relevant to this article

Fast and Facile Synthesis of 4-Nitrophenyl 2-Azidoethylcarbamate Derivatives from N-Fmoc-Protected α-Amino Acids as Activated Building Blocks for Urea Moiety-Containing Compound Library

Doi:10.1021/acscombsci.6b00160
(2017)
Molecular assembly composed of a dendrimer template and block polypeptides through stereocomplex formation

Doi:10.1039/c2cc30926b
(2012)
Rapid access to the Welwitindolinone alkaloid skeleton by cyclization of indolecarboxaldehyde substituted cyclohexanones

Doi:10.1021/ol051239t
(2005)
Magnetically retrievable nano crystalline nickel ferrite- catalyzed aerobic, ligand-free C-N, C-O and C-C cross-coupling reactions for the synthesis of a diversified library of heterocyclic molecules

Doi:10.1002/adsc.201300686
(2014)
A convenient and efficient conversion of 4-aminobenzophenone into some new 1,2,3-triazole and benzothiazole derivatives

Doi:10.1002/jccs.200500023
(2005)
Formation of an unsymmetrical dinuclear ruthenium complex with μ-H, μ-OH, and μ-κ²-CO₂ bridges and multiple reactive sites

Doi:10.1002/anie.200501335
(2005)

Article Doi