Chemistry Letters p. 441 - 444 (1983)
Update date:2022-08-04
Topics:
Uehara, Akira
Kubota, Tohru
Tsuchiya, Ryokichi
Atropisomeric chiral bisphosphine, (S)-6,6'-dimethyl-2,2'-bis(diphenylphosphinamino)biphenyl (MABP) was newly prepared, and the Rh(I) complex thereof was found to be highly effective for the asymmetric hydrogenation of 2-acetamidoacrylic acid even under 1 atm of hydrogen pressure at a temperature below 0 deg C.
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