Homolytic Fission and Scrambling Reactions of Mn2(CO)8(PCy3)2 (Cy = cyclohexyl) and Mn2(CO)8(PPh3)2

DOI: 10.1039/c39830000566

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 566 - 567 (1983)

Update date:2022-07-30

Topics:

Authors:

Poe, Anthony

Sekhar, Chandra

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830000566

The complexes Mn2(CO)8L2 (L=PCy3 and PPh3) (Cy=cyclohexyl) both react with 1,1,2,2-tetrachloroethane to form ClMn(CO)4L at rates which conform with initial homolytic fission of the Mn-Mn bond and this mechanistic assignment is confirmed by the occurence o

Full text of DOI:10.1039/c39830000566

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mn(CO)4(P(C₆H₁₁)3)I

Cas No:87431-90-1

R&D Labs maybe for 87431-90-1

Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Weifang Haiye Chemistry and Industry Co., Ltd.

website:https://member.lookchem.com/member/Authentication2.aspx?l=1

Contact:86-151-94208566

Address:South of lianmeng road,east of dadi road,houtown,shouguang city,china
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD

Relevant to this article

Total synthesis and structural elucidation of (-)-maurenone

Doi:10.1021/jo051753c
(2006)
Improved Process for Preparation of tert-Butanesulfinyl Ketimines of Hindered Ketones under Nitrogen Flow

Doi:10.1021/acs.oprd.6b00188
(2016)
Chiral Recognition of Peptide Enantiomers by Cinchona Alkaloid Derived Chiral Selectors: Mechanistic Investigations by Liquid Chromatography, NMR Spectroscopy, and Molecular Modeling

Doi:10.1021/jo0346914
(2003)
Antitumor Imidazotetrazines. 1. Synthesis and Chemistry of 8-Carbamoyl-3-(2-chloroethyl)imidazo<5,1-d>-1,2,3,5-tetrazin-4(3H)-one, a Novel Broad-Spectrum Antitumor Agent

Doi:10.1021/jm00368a016
(1984)
The first insoluble polymer-bound palladium complexes of 2-pyridyldiphenylphosphine: Highly efficient catalysts for the alkoxycarbonylation of terminal alkynes

Doi:10.1039/b512556a
(2006)
REGIO-AND STEREOSELECTIVE PALLADIUM CATALYZED AMINATION OF ALLYLIC SUBSTRATES. SYNTHESIS OF E-4-AMINO-2-ALKEN-1-OL DERIVATIVES

Doi:10.1016/S0040-4039(00)88011-9
(1983)

Article Doi