Homolytic Fission and Scrambling Reactions of Mn2(CO)8(PCy3)2 (Cy = cyclohexyl) and Mn2(CO)8(PPh3)2

DOI: 10.1039/c39830000566

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 566 - 567 (1983)

Update date:2022-07-30

Topics:

Authors:

Poe, Anthony

Sekhar, Chandra

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39830000566

The complexes Mn2(CO)8L2 (L=PCy3 and PPh3) (Cy=cyclohexyl) both react with 1,1,2,2-tetrachloroethane to form ClMn(CO)4L at rates which conform with initial homolytic fission of the Mn-Mn bond and this mechanistic assignment is confirmed by the occurence o

Full text of DOI:10.1039/c39830000566

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mn(CO)4(P(C₆H₁₁)3)I

Cas No:87431-90-1

R&D Labs maybe for 87431-90-1

Beijing Ribio Biotech Co.,Ltd

Contact:86-10-62664360

Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Changzhou Qidi Chemical Co., Ltd

website:http://www.czqdhg.com/

Contact:86-519-83382137

Address:128-1-16# HuaYuan Street,Hutang Town,Wujin District,Changzhou City,P.R.China.
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.

Relevant to this article

Total synthesis and structural elucidation of (-)-maurenone

Doi:10.1021/jo051753c
(2006)
Improved Process for Preparation of tert-Butanesulfinyl Ketimines of Hindered Ketones under Nitrogen Flow

Doi:10.1021/acs.oprd.6b00188
(2016)
Chiral Recognition of Peptide Enantiomers by Cinchona Alkaloid Derived Chiral Selectors: Mechanistic Investigations by Liquid Chromatography, NMR Spectroscopy, and Molecular Modeling

Doi:10.1021/jo0346914
(2003)
Antitumor Imidazotetrazines. 1. Synthesis and Chemistry of 8-Carbamoyl-3-(2-chloroethyl)imidazo<5,1-d>-1,2,3,5-tetrazin-4(3H)-one, a Novel Broad-Spectrum Antitumor Agent

Doi:10.1021/jm00368a016
(1984)
The first insoluble polymer-bound palladium complexes of 2-pyridyldiphenylphosphine: Highly efficient catalysts for the alkoxycarbonylation of terminal alkynes

Doi:10.1039/b512556a
(2006)
REGIO-AND STEREOSELECTIVE PALLADIUM CATALYZED AMINATION OF ALLYLIC SUBSTRATES. SYNTHESIS OF E-4-AMINO-2-ALKEN-1-OL DERIVATIVES

Doi:10.1016/S0040-4039(00)88011-9
(1983)

Article Doi