Homolytic Fission and Scrambling Reactions of Mn2(CO)8(PCy3)2 (Cy = cyclohexyl) and Mn2(CO)8(PPh3)2

DOI: 10.1039/c39830000566

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 566 - 567 (1983)

Update date:2022-07-30

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Authors:

Poe, Anthony

Sekhar, Chandra

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Article abstract of DOI:10.1039/c39830000566

The complexes Mn2(CO)8L2 (L=PCy3 and PPh3) (Cy=cyclohexyl) both react with 1,1,2,2-tetrachloroethane to form ClMn(CO)4L at rates which conform with initial homolytic fission of the Mn-Mn bond and this mechanistic assignment is confirmed by the occurence o

Full text of DOI:10.1039/c39830000566

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