Stereoelectronic Control of the Hydrolysis of a Conformationally Locked Acetal

DOI: 10.1039/P29830001627

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1627 - 1632 (1983)

Update date:2022-08-03

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Authors:

Kirby, Anthony J.

Martin, Robert J.

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Article abstract of DOI:10.1039/P29830001627

The hydrolysis of the nitrophenyltetrahydropyranyl acetal (3e; Y=H), with leaving group fixed equatorial by the trans-ring junction, is substantially slower than expected for a comparable conformationally flexible acetal.It is also slower than the hydroly

Full text of DOI:10.1039/P29830001627

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