Reagent Design and Study of Allene as a Promising Class of Reagents (Synthons) for Cycloaddition. The Site Selective and Regioselective Diels-Alder Reactions of (Phenylsulfonyl)propadiene and Alkylation of the Adducts.

DOI: 10.1021/jo00204a018

Source and publish data:

Journal of Organic Chemistry p. 512 - 517 (1985)

Update date:2022-08-04

Topics: -Reagent -Cycloaddition -Regioselective -Alkylation -Adducts

Authors:

Hayakawa, Kenji

Nishiyama, Hitoshi

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00204a018

The cycloaddtion reaction of title compound 1 with 1,3-dienes and troponoid compounds has been investigated.The reactions with dienes 2-8 proceeded in remarkable site selective and regioselective manners to give the Diels-Alder adducts 9-15 possessing an

Full text of DOI:10.1021/jo00204a018

Products guided by the article

Product name:2H-Cyclohepta[b]furan, 3,3a-dihydro-2-methylene-3-(phenylsulfonyl)-, cis-

Cas No:94371-62-7

R&D Labs maybe for 94371-62-7

Hangzhou Pharma & Chem Co.,Ltd.

Contact:+86-571-87040515

Address:No,139Qingchun Rd
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Hebei Ruishun Trade Co.,Ltd

Contact:+86-311-89850048

Address:WanDa commerce building ,yuhua district

Relevant to this article

Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C-H bond Activation as a Key Step

Doi:10.1002/chem.201502300
(2015)
A Useful Wittig Reagent for the Stereoselective Synthesis of Trans α,β-Unsaturated Thiol Esters

Doi:10.1021/jo00205a036
(1985)
Synthesis and biological activity of a stereoisomeric mixture of the mating hormone of Phytophthora

Doi:10.1016/j.tetlet.2007.04.109
(2007)
The synthesis and antitumor activity of twelve galloyl glucosides

Doi:10.3390/molecules20022034
(2015)
A panel of subunit-selective activity-based proteasome probes

Doi:10.1039/c001036g
(2010)
Palladium complexes of a P₂C = Ligand containing a central carbene moiety

Doi:10.1021/om700414t
(2007)

Article Doi