Reagent Design and Study of Allene as a Promising Class of Reagents (Synthons) for Cycloaddition. The Site Selective and Regioselective Diels-Alder Reactions of (Phenylsulfonyl)propadiene and Alkylation of the Adducts.

DOI: 10.1021/jo00204a018

Source and publish data:

Journal of Organic Chemistry p. 512 - 517 (1985)

Update date:2022-08-04

Topics: -Reagent -Cycloaddition -Regioselective -Alkylation -Adducts

Authors:

Hayakawa, Kenji

Nishiyama, Hitoshi

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00204a018

The cycloaddtion reaction of title compound 1 with 1,3-dienes and troponoid compounds has been investigated.The reactions with dienes 2-8 proceeded in remarkable site selective and regioselective manners to give the Diels-Alder adducts 9-15 possessing an

Full text of DOI:10.1021/jo00204a018

Products guided by the article

Product name:2H-Cyclohepta[b]furan, 3,3a-dihydro-2-methylene-3-(phenylsulfonyl)-, cis-

Cas No:94371-62-7

R&D Labs maybe for 94371-62-7

Huaihua Baohua Biotechnology Co.,Ltd

website:http://www.baochengchem.com

Contact:86-519-82698291

Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China

Relevant to this article

Total Synthesis of cis-Clavicipitic Acid from Asparagine via Ir-Catalyzed C-H bond Activation as a Key Step

Doi:10.1002/chem.201502300
(2015)
A Useful Wittig Reagent for the Stereoselective Synthesis of Trans α,β-Unsaturated Thiol Esters

Doi:10.1021/jo00205a036
(1985)
Synthesis and biological activity of a stereoisomeric mixture of the mating hormone of Phytophthora

Doi:10.1016/j.tetlet.2007.04.109
(2007)
The synthesis and antitumor activity of twelve galloyl glucosides

Doi:10.3390/molecules20022034
(2015)
A panel of subunit-selective activity-based proteasome probes

Doi:10.1039/c001036g
(2010)
Palladium complexes of a P₂C = Ligand containing a central carbene moiety

Doi:10.1021/om700414t
(2007)

Article Doi