Reagent Design and Study of Allene as a Promising Class of Reagents (Synthons) for Cycloaddition. The Site Selective and Regioselective Diels-Alder Reactions of (Phenylsulfonyl)propadiene and Alkylation of the Adducts.

DOI: 10.1021/jo00204a018

Source and publish data:

Journal of Organic Chemistry p. 512 - 517 (1985)

Update date:2022-08-04

Topics: -Reagent -Cycloaddition -Regioselective -Alkylation -Adducts

Authors:

Hayakawa, Kenji

Nishiyama, Hitoshi

Kanematsu, Ken

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Article abstract of DOI:10.1021/jo00204a018

The cycloaddtion reaction of title compound 1 with 1,3-dienes and troponoid compounds has been investigated.The reactions with dienes 2-8 proceeded in remarkable site selective and regioselective manners to give the Diels-Alder adducts 9-15 possessing an

Full text of DOI:10.1021/jo00204a018

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