SYNTHETIC PHOTOCHEMISTRY. XXVIII. A PHOTOCHEMICAL C5-HOMOLOGATION OF 4-ISOPROPENYLTOLUENE WITH METHYL 2,4-DIOXOPENTANOATE TO ISOLAURENE AND A FORMAL SYNTHESIS OF CUPARENE.

DOI: 10.1246/bcsj.57.3152

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3152 - 3155 (1984)

Update date:2022-07-30

Topics:

Authors:

Takeshita

Mori Mori

Nakamura

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.57.3152

Starting from the photocycloaddition of methyl 2,4-dioxopentanoate with 4-isopropenyltoluene, isolaurene was synthesized, and its further conversion to 5-cuparenone constituted the formal synthesis of cuparene. For the first time, the proto-(2 plus 2) pi

Full text of DOI:10.1246/bcsj.57.3152

Products guided by the article

Product name:Cyclobutanecarboxylic acid, 4-acetyl-1-hydroxy-2-methyl-2-(4-methylphenyl)-, methyl ester

Cas No:94827-83-5

R&D Labs maybe for 94827-83-5

Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China
Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao

Relevant to this article

NEW SYNTHETIC UTILITY OF SINGLET OXYGEN IN SULPHIDE PHOTO-OXIDATION. SELECTIVE AND STEREOSPECIFIC HYDROXYLATION α TO SULPHUR OF 4-SUBSTITUTED 3-BENZOYL-2,2-DIMETHYLTHIAZOLIDINES

Doi:10.1016/S0040-4020(01)96584-6
(1985)
The first stereoselective Pd-catalyzed addition of boronic acids onto aldehydes

Doi:10.1016/j.tetasy.2007.06.031
(2007)
Synthesis of 3-alkyl and arylapomorphines

Doi:10.1080/00397910701462773
(2007)
Reusable 1,2,4-triazolium based bronsted acidic room temperature ionic liquids as catalyst for mannich base reaction

Doi:10.1007/s10562-014-1312-7
(2014)
Benzimidazoles as potent and orally active mGlu5 receptor antagonists with an improved pk profile

Doi:10.1021/ml100215b
(2011)
Synthesis and characterization of palladium(II) complexes with chiral aminophosphine ligands: Catalytic behaviour in asymmetric hydrovinylation. Crystal structure of cis-[PdCl₂(PPh((R)-NHCHCH₃Ph)₂)₂]

Doi:10.1016/j.jorganchem.2007.02.020
(2007)

Article Doi