Mechanistic Studies on the Role of Carbon Dioxide in the Synthesis of Methylcarbamates from Amines and Dimethylcarbonate in the Presence of CO2

DOI: 10.1016/S0040-4020(01)80894-2

Source and publish data:

Tetrahedron p. 9489 - 9502 (1991)

Update date:2022-08-17

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Authors:

Aresta, Michele

Quaranta, Eugenio

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Article abstract of DOI:10.1016/S0040-4020(01)80894-2

N-Alkylmethylcarbamates have been synthesized from amines and dimethylcarbonate (DMC) in the presence of carbon dioxide.The catalytic role of CO2 in the overall process has been investigated and elucidated.Key words: carbon dioxide; organic carbamates; dimethylcarbonate; carbamic-carbonic anhydride

Full text of DOI:10.1016/S0040-4020(01)80894-2

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