The Photochemistry of Nitrosobenzene: Direct Observation of the Phenyl Radical-Nitric Oxide Triplet Radical Pair in Argon at 12 K

DOI: 10.1039/c39900000227

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Journal of the Chemical Society. Chemical communications p. 227 - 229 (1990)

Update date:2022-08-16

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Authors:

Hatton, William G.

Hacker, Nigel P.

Kasai, Paul H.

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Article abstract of DOI:10.1039/c39900000227

Photolysis of nitrosobenzene monomer in an argon matrix at 12 K efficiently yields the phenyl radical and nitric oxide as a triplet radical pair, which are characterized by IR, UV, and ESR spectroscopy; these species recombine upon warming to 25-40 K to regenerate nitrosobenzene.

Full text of DOI:10.1039/c39900000227

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