Investigation of the alkylation ability of silylated nitroalcohols

DOI: 10.1007/BF00702022

Source and publish data:

Russian Chemical Bulletin p. 1262 - 1263 (1993)

Update date:2022-08-11

Topics:

Authors:

Apasov, E. T.

Kalinin, A. V.

Ioffe, S. L.

Tartakovskii, V. A.

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Article abstract of DOI:10.1007/BF00702022

β-Nitrosubstituted trimethylsilylated alcohols RCH2-O-SiMe3 have been studied.It has been shown that the trimethylsiloxy group is sufficiently reactive only in the N-nitro derivative in which it can be replaced by a chlorine atom or dimethylamino group upon the action trimethylchlorosilane or pentamethyldisilazane, respectively.

Full text of DOI:10.1007/BF00702022

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