Journal of the Chemical Society. Chemical communications p. 933 - 934 (1980)
Update date:2022-08-15
Topics:
Beach, David L.
Kobylinski, Thaddeus P.
The first example of the use of a cyclopentadienylnickel cluster to effect catalytic oligomerization of an olefin is reported; when a benzene solution of di-μ-carbonyl-tris(cyclopentadienylnickel) is allowed to react with silica-alumina and subsequently heated to 150 degC, a highly active catalyst is formed which oligomerizes ethylene to higher olefins with turnover frequencies greater than 105 mol ethylene per mol (η5-C5H5)3Ni3(CO)2 per h.
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