Tetrahedron Letters p. 4169 - 4172 (1994)
Update date:2022-08-17
Topics:
Kamochi, Yasuko
Kudo, Tadahiro
Phenol was rapidly reduced with samarium diiodide-base system in the presence of protic solvent at room temperature to afford 3-cyclohexen-1-ol accompanied by cyclohexanol.The similar reduction of 4-methoxyphenol and 2-naphthol gave 4-hydroxycyclohexanone and 1,2,3,4-tetrahydro-2-naphthol in excellent yield, respectively.
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